标题: MOF-derived nanostructured NiFe LDHs as catalysts for Bisphenol A degradation

作者: Li, MW (Li, Mengwei); Cai, MJ (Cai, Minjuan); Brigante, M (Brigante, Marcello); Mailhot, G (Mailhot, Gilles); You, ZX (You, Zhixiong); Prevot, V (Prevot, Vanessa); Forano, C (Forano, Claude)

来源出版物: APPLIED MATERIALS TODAY 卷: 43 文献号: 102640 DOI: 10.1016/j.apmt.2025.102640 Published Date: 2025 APR

摘要: This study highlights the microwave-assisted (MW) synthesis of NiFe Layered Double Hydroxide (LDH) from the conversion of MIL-88A, an iron-based metal organic framework. The use of MW appears as a superior activation method for producing highly crystalline, monodisperse nanoparticles of MIL-88A with uniform rod-like morphology. Firstly, the identification of optimal synthesis conditions (110 degrees C, 30 min) enabled the production of MIL-88A crystals with significantly enhanced crystallinity and structural integrity, as confirmed by XRD and FTIR analyses. SEM and TEM imaging revealed smooth microrods, contrasting with the irregular structures obtained under hydrothermal synthesis conditions. The process is faster, energy-efficient, and scalable, validating its advantages over traditional methods. Secondly, MIL-88A was successfully converted into NixFe LDH via microwave heating in presence of Ni2+ nitrate and urea. This process utilized MIL-88A as both a structural template and an Fe3+ source. Under optimal conditions (110 degrees C, 60 min), complete transformation was achieved, as confirmed by XRD, which revealed the hexagonal LDH structure. SEM demonstrated petal-like LDH growth on MIL-88A rods, while nitrogen adsorption desorption analysis indicated a mesoporous structure with an increased surface area of 80 m2/g. Elemental mapping confirmed the uniform distribution of Ni, Fe, and O, highlighting the efficient integration of components. Finally, a comparative study of catalytic performance demonstrated the superior efficiency of Ni3Fe LDH/88A, achieving 81% BPA degradation within 10 min, significantly outperforming Ni3Fe LDH/COP (53%) and the precursor MIL-88A (21.8%). Kinetic modelling showed Ni3Fe LDH/ 88A higher rate constant (0.153 min-1), highlighting its enhanced activity. BPA degradation was attributed to persulfate (PS) activation by Ni2+/Fe3+ system. Reusability tests confirmed Ni3Fe LDH/88A stability, maintaining efficiency across multiple cycles with minimal structural changes. These findings emphasize the scalability and versatility of MIL-88A and NiFe LDH/88A for environmental remediation, positioning them as promising materials for advanced oxidation processes and sustainable catalytic applications.

作者关键词: NiFe layered double hydroxides; MIL-88A; Microwave-assisted conversion; Bisphenol A catalytic degradation

KeyWords Plus: LAYERED DOUBLE HYDROXIDE; METAL-ORGANIC FRAMEWORKS; ADVANCED OXIDATION PROCESSES; PHOTOCATALYTIC DEGRADATION; EFFICIENT DEGRADATION; ACTIVATION; PERSULFATE; WATER; FE; PERFORMANCE

地址: [Li, Mengwei; Cai, Minjuan; You, Zhixiong] Wuhan Univ, Sch Resource & Environm Sci, Wuhan, Peoples R China.

[Li, Mengwei; Cai, Minjuan; Brigante, Marcello; Mailhot, Gilles; Prevot, Vanessa; Forano, Claude] Univ Clermont Auvergne, Inst Chim Clermont Ferrand, CNRS, Clermont Auvergne INP, F-63000 Clermont Ferrand, France.

通讯作者地址: You, ZX (通讯作者)，Wuhan Univ, Sch Resource & Environm Sci, Wuhan, Peoples R China.

Prevot, V; Forano, C (通讯作者)，Univ Clermont Auvergne, Inst Chim Clermont Ferrand, CNRS, Clermont Auvergne INP, F-63000 Clermont Ferrand, France.

电子邮件地址: zyou@whu.edu.cn; vanessa.prevot@uca.fr; claude.forano@uca.fr

影响因子：7.2